含苯环亲水共聚物形态及溶液荧光  

Fluorescences and Forms of Water Soluble Copolymers of Styrelle and Acrylic Acid

作　　者：鸟云其木格 吴红英[1] 博.格日勒图[1] 吴哈申[1] 

机构地区：[1]内蒙古师范大学化学系,呼和浩特010022

出　　处：《高等学校化学学报》1997年第3期492-494,共3页Chemical Journal of Chinese Universities

基　　金：内蒙古科委自然科学基金;内蒙古教育厅资助

摘　　要：研究含芳环（生色团）的亲水性高分子对于了解高分子结构和性质之间的关系，开发新型发光材料很有意义[1.2]．前文[3.4]借报道了N-乙烯基咋冷丙烯酸共聚物（NVC－AA）的合成及发光性能研究，本文报道含苯环亲水高分子苯乙烯一丙烯酸共聚物（ST－AA）的微观结构与荧光特性?..The relationship between the fluorescences and structrue of the copolymer of styrene and acrylic acid (ST-AA) was investigated in aqueous solution. When the concentration of ST-AA increased, there exist monomer fluorescence (λex = 258nm, λcm= 27O nm) and excimer fluorescence(λcm= 375 nm). The excimer fluorescence intensities increased with increasing the concentration of ST-AA and with decreasing pH values. When trace amount of molybdenum compound[Mo3O2(O2CCH3), (H2O)3]. Br2. 2H2O, was added into the aqueous solution of ST-AA, the excimer fluorescence intensities were increased

关 键 词：苯乙烯 丙烯酸 共聚物 钼簇合物 荧光 亲水 

分 类 号：TQ325.2[化学工程—合成树脂塑料工业]