长脂肪碳链卟啉的合成及其LB膜的制备和气敏性质研究  

Synthesis of Long Aliphatic Carbochain Porphyrins and Their LB Films and Study on Their Gas Sensitivity

作　　者：刘玉文[1] 赵玉娥[1] 王立波[1] 王润伟[1] 梁宏斌 朱浩 曹锡章 

机构地区：[1]吉林大学化学系,长春130023

出　　处：《高等学校化学学报》1997年第5期682-684,共3页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金

摘　　要：Tetranicotinamidephenyl porphyrin(TNAPP) reacts with n-C16H33Br and n-C12H25 Br, respectively to yield the products tetra (N-hexadecyl nicotinamide phenyl) porphyrin bromide (THNAPPBr) and tetra-(N-dodecylnicotinamide phenyl ) porphyrin bromide. Its cobalt complex and zinc complex are also prepared. Those porphyrins and metal porphyrins have good film-forming properties. The gas sensitivity studies show that the six kinds of porphyrins are sensitive to NH3 and has a fine selectivity.Tetranicotinamidephenyl porphyrin(TNAPP) reacts with n-C16H33Br and n-C12H25 Br, respectively to yield the products tetra (N-hexadecyl nicotinamide phenyl) porphyrin bromide (THNAPPBr) and tetra-(N-dodecylnicotinamide phenyl ) porphyrin bromide. Its cobalt complex and zinc complex are also prepared. Those porphyrins and metal porphyrins have good film-forming properties. The gas sensitivity studies show that the six kinds of porphyrins are sensitive to NH3 and has a fine selectivity.

关 键 词：卟啉 LB膜 气敏性 双亲性卟啉 衍生物 

分 类 号：O626.13[理学—有机化学] O659[理学—化学]