有机膦配位镍催化剂的乙烯齐聚研究 Ⅱ.用于制1-丁烯的催化剂  

The Ethylene Oligomerization on the Nickel Catalysts Coordinated with Organophosphorus Ⅱ The Catalysts for 1 Butene Production

作　　者：宋焕玲[1] 孙衍文[1] 刘铁元 夏春谷[1] 何荔[1] 李达刚[1] 

机构地区：[1]中国科学院兰州化学物理研究所

出　　处：《分子催化》1997年第4期301-304,共4页Journal of Molecular Catalysis(China)

摘　　要：有机膦配位镍催化剂的乙烯齐聚研究Ⅱ．用于制１丁烯的催化剂宋焕玲孙衍文刘铁元夏春谷何荔李达刚（中国科学院兰州化学物理研究所兰州７３００００）关键词有机膦镍催化剂乙烯齐聚分类号Ｏ６４３．３２乙烯齐聚的主要产物是线性α烯烃，其碳数分布符合Ｓｃｈｕｌｚ?..A new method was used to synthesize the soluble organophosphorus ligand sodium 9 phosphabicyclo nonyl propanate. Ethylene oligomerization with a catalyst containing consisting of this ligand and dichloronickel prepared in 1,4 butyl glycol by NaBH 4 reduction was examined. The results indicate that this soluble nickel phosphine catalyst had good catalytic activity (4 kg/(gNi·h)) and linear selectivity (1 butylene>90%).

关 键 词：有机膦 镍 催化剂 乙烯 齐聚 丁烯 

分 类 号：O643.36[理学—物理化学] O643.32[理学—化学]