以BF3(CH3)2O/CF3COOH共引发剂合成端羟基聚环氧氯丙烷的探讨  

The Synthesization of Polyepichlorohydrin by Initiator of BF_3(CH_3)_2O/CF_3COOH

作　　者：高和军[1] 段明[2] 胡星琪[2] 高志飞[3] 

机构地区：[1]西华师范大学化学化工学院,四川南充637002 [2]西南石油大学油气藏地质及开发工程国家重点实验室,四川成都610500 [3]西南石油大学化学化工学院

出　　处：《高分子材料科学与工程》2008年第3期56-59,共4页Polymer Materials Science & Engineering

摘　　要：通过改变传统的引发体系,采用BF3.(CH3)2O/CF3COOH合成了无色透明且分子量较高的端羟基聚环氧氯丙烷(PECH),利用核磁共振、红外光谱等手段对产物的化学结构进行了详细的分析,同时考察了BF3.(CH3)2O及CF3COOH用量对PECH相对黏度的影响,探讨了TCA提高产物透明度的作用。结果表明,合成了主链以头尾连接为主,头头及尾尾连接为辅的PECH。The paper presented the synthesization of hydroxyl terminated polyepichlorohydrin by new coinitiator of CF3COOH/BF3 （CH3）2O. The chemical constitution was discussed by methods of IR, 1^H-NMR and 13^C-NMR. And the impact of the amount of the boron trifluoride diethyl etherate and TCA was discussed and the role of increasing relative molecular weight and transparency of TCA was discussed in the paper at the same time. The chemical constitution of PECH indicates that the main chemical constitution of hydroxyl terminated polyepichlorohydrin is H-T, and the subordination chemical constitutions are H-H and T-T.

关 键 词：端羟基聚环氧氯丙烷 共引发剂 相对黏度 

分 类 号：TQ314.241[化学工程—高聚物工业]