Synthesis of di-μ-oxo-tetra-(α-pentyloxy) tin(Ⅳ) phthalocyanine  

作　　者：Yi Ru Peng Yu Hong Cao Pei Feng Chen Xiao Xia Huang 

机构地区：[1]College of Chemistry ＆ Material Science, Fujian Normal University, Fuzhou 350007, China

出　　处：《Chinese Chemical Letters》2008年第3期273-276,共4页中国化学快报（英文版）

摘　　要：Axially substituted tin phthalocyanines, namely dichloride-tetra-（α-pentyloxy） tin （Ⅳ） phthalocyanine 2, dihydroxy-tetra-（α-pentyloxy） tin （Ⅳ） phthalocyanine 3 and its dimmer di-μ-oxo-tetra-（α-pentyloxy） tin（Ⅳ） phthalocyanine 4 were synthesized. The catalytic effect of H2O-free CaCl2 in quinoline was used for condensation of dihydroxy tin phthalocyanine 3 to the cofacially array dimmer 4. Their structures were characterized by UV-vis, IR, elemental analysis, MS, as well as ^1HNMR spectroscopy.Axially substituted tin phthalocyanines, namely dichloride-tetra-（α-pentyloxy） tin （Ⅳ） phthalocyanine 2, dihydroxy-tetra-（α-pentyloxy） tin （Ⅳ） phthalocyanine 3 and its dimmer di-μ-oxo-tetra-（α-pentyloxy） tin（Ⅳ） phthalocyanine 4 were synthesized. The catalytic effect of H2O-free CaCl2 in quinoline was used for condensation of dihydroxy tin phthalocyanine 3 to the cofacially array dimmer 4. Their structures were characterized by UV-vis, IR, elemental analysis, MS, as well as ^1HNMR spectroscopy.

关 键 词：Axially substituted tin （Ⅳ） phthalocyanine DIMMER Synthesis Characterization 

分 类 号：O62[理学—有机化学]