乙二醇单二环戊烯基醚丙烯酸酯的合成及其氧化聚合性质的研究  

Study on Synthesis of Ethylene Glycol Mono dicyclopentenyl Ether Acrylate and its Oxidative Polymerization Property

作　　者：刘德辉[1] 铁宏[1] 孙武权 雷克微 

机构地区：[1]沈阳化工学院精细化工系

出　　处：《沈阳化工学院学报》1997年第2期113-119,共7页Journal of Shenyang Institute of Chemical Technolgy

摘　　要：用二环戊二烯和乙二醇进行加成反应合成乙二醇单二环戊烯基醚，并说明了此反应的原理．再用乙二醇单二环戊烯基醚同丙烯酸反应得到乙二醇单二环戊烯基醚丙烯酸酯．得出了合理的合成工艺条件，测定了用环烷酸钴为催化剂时乙二醇单二环戊烯基醚丙烯酸酯的氧化聚合速度，解释氧化聚合原理，测试其低温下游离基聚合特性．In this paper, ethylene glycol mono dicyclopentenyl ether is synthesised by addition reaction of dicyclopentadiene and ethylene glycol, and the mechanism of this reaction is explained. The title compound is obtained with ethylene glycol mono dicyclopentenyl ether and acrylic acid,and a reasonable synthesis process is given. Oxidative polymerization rate of ethylene glycol mono dicyclopentenyl ether acrylate and its radical polymerization property at low temperature are investigated, and the mechanism of oxidative polymerization is discussed.

关 键 词：乙二醇 二环戊烯基醚 丙烯酸酯 氧化聚合 

分 类 号：O623.624[理学—有机化学]