Y(ClO_4)_3·3H_2O-B15C5-C_2H_5OH体系的相平衡研究及固态配合物的合成与表征  

STUDY ON PHASE EQUILIBRIUM OF THE SYSTEM Y(ClO 4) 3·3H 2O B15C5 C 2H 5OH AND SYNTHETIC AND CHARACTERISTIC OF COORDINATION COMPOUNDS

作　　者：温德才 薛岗林[2] 何水样[2] 任德厚[2] 

机构地区：[1]福建龙岩师专化学系 [2]西北大学化学系

出　　处：《化学研究与应用》1997年第4期392-396,共5页Chemical Research and Application

摘　　要：Ｙ（ＣｌＯ４）３３Ｈ２Ｏ－Ｂ１５Ｃ５－Ｃ２Ｈ５ＯＨ体系的相平衡研究及固态配合物的合成与表征温德才（福建龙岩师专化学系龙岩３６４０００）薛岗林何水样任德厚（西北大学化学系西安７１００６９）关键词三元体系相平衡配合物冠醚Ｂ１５Ｃ５三水高氯酸钇中图分类号６...The solubilities of ternary system,Y(ClO 4) 3·3H 2O B15C5 C 2H 5OH,have been investigated at 25℃ by a semimicro method of phase equilibrium,the refractive indexes of saturated solutions have been determined.There are three coordination compounds formed in the system at 25℃.The compositions of the three coordination compounds are:4Y(ClO 4) 3·3B15C5·12H 2O·3.5C 2H 5OH(Ⅰ),Y(ClO 4) 3·B15C5·3H 2O·1.5C 2H 5OH(Ⅱ) and Y(ClO 4) 3·2B15C5·3H 2O·C 2H 5OH(Ⅲ).The behavior of water in this system in phase equilibrium has been examined.The solid coordination compounds have been prepared on basis of investigation of phase equilibrium.Three coordination compounds have been characterized by chemical analysis,IR,conductivity measurements and TG DTG.

关 键 词：相平衡 配合物 冠醚B15C5 三水高氯酸钇 钇 

分 类 号：O642.42[理学—物理化学] O614.322[理学—化学]