[Cu(DMTZB)_4](ClO_4)_2的合成及晶体结构(DMTZB=3,3-二甲基-(1H-1,2,4-三唑)-2-丁酮)  

SYNTHESIS AND CRYSTAL STRUCTURE OF COMPLEX[Cu(DMTZB) 4](ClO 4) 2

作　　者：顾建胜[1] 李宝龙[1] 卞国庆[1] 郁开北[2] 

机构地区：[1]苏州大学化学系 [2]中科院成都分院分析测试中心

出　　处：《化学研究与应用》1997年第3期294-297,共4页Chemical Research and Application

摘　　要：［Ｃｕ（ＤＭＴＺＢ）４］（ＣｌＯ４）２的合成及晶体结构（ＤＭＴＺＢ＝３，３－二甲基－（１Ｈ－１，２，４－三唑）－２－丁酮）顾建胜李宝龙＊卞国庆（苏州大学化学系苏州２１５００６）郁开北（中科院成都分院分析测试中心成都６１００４１）关键词三唑铜配合物晶体...The title complex was synthesized by reaction of 3,3 dimethyl 1 (1H 1,2,4 triazol 1 yl) 2 butanone with copper perchlorate (Cu(ClO 4) 2·6H 2O) and obtained in the form of single crystals C 32 H 52 N 12 Cl 12 O 12 Cu,Mr=931.30.The crystal structure was determined by X-ray diffraction method.This compound crystallized in the triclinic system,space group p 1 with unit cell dimensions a=9.070(1), b =11.291(1), c =12.157(2), α =94.85(1)°, β =102.92(1)°, γ =109.74(1)°, V =1124.6(2) 3, Z =1,the final R value is 0.0405.The structure analysis shows that copper atom was coordinated by four N 4 atoms of the triazole group to form a planar quadrilateral structure and the copper atom is located in the symmetry centre of the molecule.

关 键 词：三唑 铜配合物 晶体结构 配合物 

分 类 号：O626.26[理学—有机化学] O614.121[理学—化学]