甲酸桥联四核锰配合物[Mn_4(O_2CH)_4(phen)_8](ClO_4)_4·6H_2O的水热合成和晶体结构(英文)  

Hydrothermal Synthesis and Crystal Structure of a Tetranuclear Manganese(Ⅲ) Complex Bridged by Formate [Mn_4(O_2CH)_4(phen)_8](ClO_4)_4·6H_2O

作　　者：陈满生[1] 蔡金华[2] 邓奕芳[1] 邝代治[1] 张春华[1] 唐斯萍[1] 

机构地区：[1]衡阳师范学院化学与材料科学系,衡阳421008 [2]河池学院化学与生命科学系,宜州546300

出　　处：《无机化学学报》2008年第3期479-482,共4页Chinese Journal of Inorganic Chemistry

基　　金：湖南省重点学科建设项目;衡阳师范学院青年骨干基金(2007);衡阳市科技局资助项目(No.2007KJ004)

摘　　要：The title compound, [Mn4(O2CH)4(phen)8](ClO4)4·6H2O (1), where phen=1,10-phenanthroline, was synthes-ized and its crystal structure was determined by X-ray diffraction structure analysis. The crystal is of monoclinic, space group P2/c with a=1.928 0(16) nm, b=1.297 0(11) nm, c=2.126 4(18) nm, V=5.242 2(8) nm3, Z=2, Mr=2 347.36, Dc=1.487 g·cm^-3, μ=0.659 mm^-1, F(000)=2 400, Rint=0.043 7, R=0.052 3, wR=0.118 6. The Mn atoms are octahed-rally coordinated by two O atoms of two ligands and four N atoms of two 1,10-phenanthroline molecules. The carboxyl group coordinates to Mn(Ⅲ) in the bridging bidentate mode. CCDC: 675520.The title compound, [Mn4（O2CH）4（phen）8]（ClO4）4·6H2O （1）, where phen=1,10-phenanthroline, was synthes-ized and its crystal structure was determined by X-ray diffraction structure analysis. The crystal is of monoclinic, space group P2/c with a=1.928 0（16） nm, b=1.297 0（11） nm, c=2.126 4（18） nm, V=5.242 2（8） nm3, Z=2, Mr=2 347.36, Dc=1.487 g·cm^-3, μ=0.659 mm^-1, F（000）=2 400, Rint=0.043 7, R=0.052 3, wR=0.118 6. The Mn atoms are octahed-rally coordinated by two O atoms of two ligands and four N atoms of two 1,10-phenanthroline molecules. The carboxyl group coordinates to Mn（Ⅲ） in the bridging bidentate mode. CCDC： 675520.

关 键 词：锰配合物 晶体结构 甲酸 水热合成 

分 类 号：O614.711[理学—无机化学]