10,11-二氢化-7-(4-羟基苯基)-10,10-二甲基苯并[b][1,7]菲咯啉-8(7H,9H,12H)-酮的合成和晶体结构  

Synthesis and Crystal Structure of 10,11-Dihydro-7-(4-hydroxyphenyl)-10,10-dimethylbenzo[b][1,7]phenanthroline-8(7H,9H,12H)-one

作　　者：张梅梅[1] 郑维发[1] 

机构地区：[1]徐州师范大学江苏省药用植物生物技术重点实验室,江苏徐州221116

出　　处：《徐州师范大学学报（自然科学版）》2008年第1期48-51,共4页Journal of Xuzhou Normal University(Natural Science Edition)

基　　金：江苏省高校自然科学基金资助项目(04KJB150139)

摘　　要：标题化合物C24H22N2O2是由N-(4-羟基苯亚甲基)喹啉-5-胺和5,5-二甲基-1,3-环己二酮在氯化三乙基苄基铵(TEBAC)催化下以水作溶剂反应而得.结构通过单晶X射线衍射分析确定,其晶体属于正交晶系,空间群c2221,a=1.6558(2),b=1.6547(2),c=2.8975(3)nm,Mr=370.44,V=7.9387(16)nm3,Dc=1.240g/cm3,Z=16,μ(MoKα)=0.7900cm-1,F(000)=3136.晶体结构用直接法解出,使用全矩阵最小二乘法对原子参数进行修正,最后的偏离因子R=0.0380,Rw=0.0862.The title compound C24 H22 N2O2 has been synthesized by the reaction of N-arylidenenaphthalen-2-amine with 5,5-dimethyl-1,3-cyclohexadione water catalyzed by triethylbenzylammonium chloride（TEBAC）. Its structure was determined by single crystal X-ray diffraction. The crystal is orthorhombic,space group c 2221 with a=1.655 8（2）, b=1.654 7（2）, c=2. 897 5（3） nm, Mr= 370.44, V=7. 938 7（16） nm^3, Dc=1.240 g/cm^3 , Z=16, μ（Mo Kα）=0. 790 0 cm^-1 ,F（000）=3 136. The structure was solved by direct methods and refined by full-matrix least-squares method to the final R=0. 038 0,Rw=0. 086 2.

关 键 词：菲咯啉 氯化三乙基苄基铵 合成 晶体结构 

分 类 号：O623.626[理学—有机化学]