常见有机物对催化臭氧化降解水中硝基苯的影响  

Effect of Organic Compounds on the Degradation of Nitrobenzene in Aqueous Solution by Catalytic Ozonation

作　　者：赵雷[1] 马军[1] 刘正乾[1] 孙志忠[2] 侯艳君[1] 

机构地区：[1]哈尔滨工业大学市政环境工程学院,哈尔滨150090 [2]黑龙江大学化学化工与材料学院,哈尔滨150080

出　　处：《环境科学》2008年第5期1233-1238,共6页Environmental Science

基　　金：国家自然科学基金项目(50378028)

摘　　要：考察了有机物甲醛、甲醇、甲酸和邻苯二甲酸二丁酯对单独臭氧氧化和蜂窝陶瓷催化臭氧化工艺去除水中硝基苯降解效果的影响规律.单独臭氧氧化和蜂窝陶瓷催化臭氧化对硝基苯的去除率随着甲醛浓度的升高（0-12 mg·L^-1）分别降低了11.6%和9.6%;2种工艺对硝基苯的去除率都随着甲醇浓度的增加（0-16 mg·L^-1）先增高再降低,单独臭氧氧化和蜂窝陶瓷催化臭氧化分别在浓度为2 mg·L^-1和4 mg·L^-1时去除率达到最大值;随着甲酸浓度的增加（0-8 mg·L^-1）去除率也都先增高再降低,单独臭氧氧化和蜂窝陶瓷催化臭氧化分别在浓度为0.5 mg·L^-1和2 mg·L^-1时去除率达到最大值;低浓度的甲醇和甲酸促进了硝基苯的降解,高浓度的甲醇和甲酸抑制了硝基苯的降解.单独臭氧氧化和蜂窝陶瓷催化臭氧化在邻苯二甲酸二丁酯浓度增加（0-10 mg·L^-1）的情况下对硝基苯的去除率分别降低了19.7%和18.6%.We investigated the effects of organic compounds on the processes of ozonation alone and ceramic honeycomb-catalyzed ozonation for the degradation of nitrobenzene in aqueous solution, including formaldehyde, methanol, formic acid and dibutyl phthalate. The results indicated that degradation rate of ozonation alone and ceramic honeycomb-catalyzed ozonation decreased by 11.6 % and 9.6 % with the increase of the concentration of formaldehyde （0-12 mg·L^-1 ）. The degradation rates of the two processes both increased firstly and decreased subsequently with the increase of the concentration of methanol （0-16 mg·L^-1 ）. The degradation rate of ozonation alone reached the climax at the concentration of methanol 2 mg·L^-1 , and that of ceramic honeycomb-catalyzed ozonation reached the culmination at the concentration of methanol 4 mg·L^-1 under the same experimental condition. With the increase of the concentration of formic acid （ 0-8 mg·L^-1 ）, the degradation rates also increased firstly and decreased subsequently, and those of ozonation alone and ceramic honeycomb-catalyzed ozonation reached the vertex, respectively, at the concentration of methanol 0.5 mg·L^-1 and 2 mg·L^-1 . At the lower concentration, methanol and formic acid could accelerate the degradation of nitrobenzene, however, the reaction was retarded at higher concentrations of methanol and formic acid. The degradation rates of ozonation alone and ozonation/ceramic honeycomb both declined by 19.7 % and 18.6 % with the increase of the concentration of dibutyl phthalate （0-10 mg·L^-1 ）.

关 键 词：催化臭氧化 蜂窝陶瓷 降解 硝基苯 甲醛 甲醇 甲酸 邻苯二甲酸二丁酯 

分 类 号：X703.1[环境科学与工程—环境工程]