反渗透复合膜研究(Ⅱ)初生态膜的原位改性  

Reverse osmosis composite membrane(Ⅱ)In situ modification of initial TFC membrane

作　　者：周勇[1] 俞三传[2] 高从堦[1] 

机构地区：[1]杭州水处理技术研究开发中心,浙江杭州310012 [2]浙江理工大学,浙江杭州310027

出　　处：《化工学报》2008年第5期1190-1193,共4页CIESC Journal

基　　金：国家重点基础研究发展计划项目(2003CB615700)~~

摘　　要：Initial reverse osmosis composite membrane(IniM) is a thin-film-composite(TFC) membrane prepared through the interfacial polymerization technique without post-treatment,such as water washing,heating,etc.Trimesoyl chloride(TMC) and m-phenylenediamine(MPD) were used to prepare some IniMs through the interfacial polymerization technique on the polysulphone supporting membrane without heat-treatment and washing.Then the in situ modification was performed with tetraethylenepentamine(TEPA) on the surface of IniMs.Modified membranes were characterized by using X-ray photoelectronic spectroscopy(XPS),contacting angle and permeation experiments with salt water of different pH values.The results showed that tetraethylenepentamine reacted with acyl chloride(—COCl) on the surface of IniM,because the ratio of O/N of the modified membrane surface was lower than that of unmodified membrane.Furthermore,the contacting angle of modified membrane was larger than that of unmodified membrane.It is interesting that the water flux and rejection of modified membrane decreased with increasing pH value for sodium chloride solution,while the unmodified membrane was just on the contrary.The reason was that functional groups on the modified and unmodified membrane were different,the former were amino(—NH2) and imino(NH),and the latter was carboxyl(—COOH).Initial reverse osmosis composite membrane （IniM） is a thin-film-composite （TFC） membrane prepared through the interracial polymerization technique without post-treatment, such as water washing, heating, etc. Trimesoyl chloride （TMC） and m-phenylenediamine （MPD） were used to prepare some IniMs through the interracial polymerization technique on the polysulphone supporting membrane without heattreatment and washing. Then the in situ modification was performed with tetraethylenepentamine （TEPA） on the surface of IniMs. Modified membranes were characterized by using X-ray photoelectronic spectroscopy （XPS）, contacting angle and permeation experiments with salt water of different pH values. The results showed that tetraethylenepentamine reacted with acyl chloride （--COCl） on the surface of IniM, because the ratio of O/N of the modified membrane surface was lower than that of unmodified membrane. Furthermore, the contacting angle of modified membrane was larger than that of unmodified membrane. It is interesting that the water flux and rejection of modified membrane decreased with increasing pH value for sodium chloride solution, while the unmodified membrane was just on the contrary. The reason was that functional groups on the modified and unmodified membrane were different, the former were amino （--NH2） and imino （-NH）, and the latter was carboxyl （--COOH）.

关 键 词：反渗透复合膜 均苯三甲酰氯 初生态膜 原位改性 

分 类 号：TQ028.8[化学工程]