菲氧化制取菲醌方法及其动力学性质研究  

A Study on the Oxidation and Kinetics Property of Crude Phenanthrene to Phenanthrenequinone

作　　者：贾晓辉[1] 罗虹[1] 刘传湘[1] 

机构地区：[1]南华大学化学化工学院,衡阳421001

出　　处：《染料与染色》2008年第2期41-44,共4页Dyestuffs and Coloration

摘　　要：本文研究了以工业菲为原料,卤素化合物作为氧化剂氧化菲合成菲醌的氧化体系,确定了影响此反应的主要因素和最佳反应条件,并对其反应机理进行了初步探讨,测定了氧化反应的一些动力学参数。Phenanthrenequinone was prepared by oxidation of phenanthrene with halogen compound, the chief influential factors and the optimum processing condition of this reaction was obtained. The mechanism of the reaction by potassium hydroxide-precipitated was discussed, and the reaction kinetic parameters was measured.

关 键 词：菲 合成 菲醌 动力学 

分 类 号：O625[理学—有机化学]