结构可控的功能化聚丙烯嵌段共聚物的应用研究  

Studies on applications of well-defined functional polypropylene copolymers

作　　者：张辽云[1] 胡友良[2] 

机构地区：[1]中国科学院研究生院,北京100049 [2]中国科学院化学研究所,北京100080

出　　处：《中国科学院研究生院学报》2008年第3期334-339,共6页Journal of the Graduate School of the Chinese Academy of Sciences

基　　金：国家自然科学基金项目(50573081,20304017,50373048,20334030)资助

摘　　要：利用差示扫描量热仪及扫描电子显微镜,分别对结构可控聚丙烯-b-聚甲基丙烯酸甲酯共聚物和聚丙烯-b-聚苯乙烯共聚物用于聚烯烃共混体系的热性能及相容性进行了研究.实验结果表明,这些功能化的聚丙烯嵌段共聚物基本上保持了原有聚丙烯高熔点等优良特性,并对它们相应共混体系有明显的增容作用.另外,这些功能化的聚丙烯嵌段共聚物能提高它们相应共混体系的弯曲强度和弯曲模量等力学性能.Differential scanning calorimeter and scanning electron microscopy were used to study effect of welldefined functional i-PP-b-PMMA block copolymer in PP/PMMA blends and that of i-PP-b-PS block copolymer in PP/PS blends. The experimental results showed these functional polypmpylene copolymers maintained characteristics of high melting point owned by starting isotactic polypmpylene polymers, and were clearly proven to be effective compatibilizer in PP/PMMA blends and PP/PS blends. In addition, i-PP-b-PMMA and i-PP-b-PS could increase bending strength and bending modulus of corresponding blending systems.

关 键 词：聚丙烯嵌段共聚物 热性能 相容性 弯曲性能 

分 类 号：O632.12[理学—高分子化学]