某些腈代及酰胺代多面体硼烷阴离子的电、热性质  

Electrical and thermal properties of some nitrile and acidamine derivatives of polyhedral borane anion

作　　者：朱伟明[1] 张国敏[1] 张伦 

机构地区：[1]云南师范大学化学系,武汉大学化学系

出　　处：《云南师范大学学报（自然科学版）》1997年第4期73-76,共4页Journal of Yunnan Normal University:Natural Sciences Edition

摘　　要：本文合成了１１个新的腈代及酰胺代多面体硼烷阴离子衍生物Ｍ［ＢｎＨｎ－１ＮＣＲ］和Ｍ［ＢｎＨｎ－１ＮＨ２ＣＯＲ］（Ｍ＝Ｅｔ４Ｎ、ＦｃＣＨ２ＮＭｅ３，Ｒ＝－ＣＨ３、－ＣＨ＝ＣＨ２，ｎ＝１０、１２），并用ＩＲ、ＥＡ、ＵＶ表征其结构。通过对这些化合物的电导及差热性质的研究。In this paper, 11 new nitrile and acidsmine derivatives of polyhedral borane anion M(BnHn-1NCR) and M(BnHn-1NH_2COR)(in which M is Et4N or FcCH_2NMe3, n is 10 or 12, R is CH_3- or CH_2=CH- respectively) have been syntheszed and characterized by their physical properties, IR, UV and elemental analyses. The thermal stability and electrical conductivities of these compounds also have been studied, and their regularity is given. 

关 键 词：多面体 硼烷阴离子 电导 热稳定性 腈代 酰胺代 

分 类 号：O627.31[理学—有机化学]