稀土钒磷酸盐薄膜的制备和发光性质研究  

Preparation and Luminescent Properties of the Rare Earth Phosphors Thin Films

作　　者：曹铁平[1] 李跃军[1] 于敏[2] 

机构地区：[1]白城师范学院化学系,吉林白城137000 [2]东北师范大学化学学院,吉林长春130024

出　　处：《河北师范大学学报（自然科学版）》2008年第3期349-353,共5页Journal of Hebei Normal University：Natural Science

基　　金：国家自然科学基金(50225205;20271048)

摘　　要：利用Pechini溶胶-凝胶法在石英玻璃基底上成功镀制了稀土离子Eu3+掺杂的YVxP1-xO4和RVO4(0≤x≤1;R=Y,La,Gd)纳米发光薄膜,研究了x值和不同的R3+对Eu3+发光的影响.结果表明,在YVxP1-xO4/Eu3+(0≤x≤1)薄膜中,随着x值的增加,R3+发光强度增大,Eu3+的红橙比随之增大,VO43-的蓝光发射减弱.YVx P1 - x O4 and RVO4 （0≤x≤1 ; R = Y, La, Gd） nano-luminescence thin films clopecl with me rare earth ions Eu^3＋ were successfully prepared by the Pechini sol-gel method on quartz glass substrates and investigated the x value and different R^3 ＋ ions influence on the luminescence of rare earth ions Eu^3 ＋ . It is found that in the thin films of YVxP1-xO4 /Eu^3 ＋ （0≤x≤1 ）, the R^3 ＋ emission intensity and the red-to-yellow intensity ratio （R/Y） of Eu^3＋ increase as the x value increases,but the blue luminescence emission of VO4^3- decreases.

关 键 词：稀土离子 掺杂 薄膜 发光 

分 类 号：O614.3[理学—无机化学]