铜催化碳-杂原子双键不对称硅氢加成反应的研究进展  

Progress in Asymmetric Hydrosilylation of Carbon-Heteroatom Unsaturated Double Bond Compounds by Copper Catalyst

作　　者：陈玲珍[1] 彭家建[1] 厉嘉云[1] 白赢[1] 邱化玉[1] 来国桥[1] 

机构地区：[1]杭州师范大学有机硅化学及材料技术教育部重点实验室,杭州310012

出　　处：《有机化学》2008年第5期761-767,共7页Chinese Journal of Organic Chemistry

摘　　要：总结了近二十年来铜催化碳-杂原子双键不对称硅氢加成的研究近展,概括了手性铜配合物催化体系催化简单酮﹑α,β-不饱和酮酯和亚胺的不对称硅氢加成,并阐述了不对称硅氢加成的催化机理.The recent advances in asymmetric hydrosilylation of carbon-heteroatom unsaturated double bond compounds by copper catalysts were summarized. The performances of a variety of different substrates which were catalyzed by the combination of copper complexes and chiral ligand were analyzed. The possible mechanisms of asymmetric hydrosilylation were also discussed.

关 键 词：手性铜配合物 不对称硅氢加成 酮类化合物 机理 

分 类 号：O643.32[理学—物理化学]