烟酮合成条件的优化  

Optimization for the Synthetic Conditions of Tobacco Ketone

作　　者：许炎妹[1] 陈玉珍[1] 王建林[1] 王晓杰[1] 侯守君[1] 

机构地区：[1]郑州轻工业学院材料与化学工程学院,河南郑州450002

出　　处：《广东化工》2008年第5期40-41,60,共3页Guangdong Chemical Industry

摘　　要：文章研究了30%的双氧水在不同pH、溶剂、温度和催化剂条件下氧化异佛尔酮为2,3-氧化异佛尔酮的反应,同时优化出了后者分别在浓盐酸或硫酸作用下水解得到烟酮的最佳条件。该合成方法收率比文献报道有所提高。The oxidation reaction of isophorone with 30 % H2O2 to 2,3-epoxyisophorone was investigated by changing the pH, solvent, temperature and catalyst. Meantime, the hydrolysis of 2,3-epoxyisophorone to tobacco ketone was studied. The yields for two steps were enhanced, comparing with the reported method.

关 键 词：异佛尔酮 氧化 合成 烟酮 

分 类 号：TQ013.1[化学工程] TQ656.5