具磷灰石假象绿松石的热性能  

Thermal Property of the Apatite Pseudomorphic Turquoise

作　　者：陈全莉[1] 亓利剑[1] 袁心强[1] 陈敬中[2] 

机构地区：[1]中国地质大学珠宝学院,湖北武汉430074 [2]中国地质大学材料科学与化学工程学院,湖北武汉430074

出　　处：《地球科学（中国地质大学学报）》2008年第3期416-422,共7页Earth Science-Journal of China University of Geosciences

基　　金：湖北省自然科学基金项目(No.2005ABA005);中国地质大学研究生学术创新与探索基金

摘　　要：绿松石的热性能分析在对其水的结构特征、呈色机理等的研究中具有重要指示作用.采用热重-差热分析(TG-DSC)、红外光谱(IR)和X-射线粉晶衍射(XRD)分析方法,对安徽马鞍山具磷灰石假象绿松石的热性能特征进行了研究.研究结果显示从室温到1100℃,假象绿松石的热相变可划分为6个变化阶段:100～200℃时,为吸附水脱水阶段;250～330℃,假象绿松石中羟基和晶格水分子脱失;330～750℃为非晶态物相阶段;约750℃时为新物相形成阶段;750～1100℃为具磷石英结构磷酸铝的形成阶段;1100℃时磷酸铝的结晶有序度增加.假象绿松石结构及水的存在形式、总量和结合方式制约和影响着颜色的变化.The study of the apatite pseudomorphic turquoise＇s thermal property plays a significant role in the investigation of the coloring mechanism and the structural characteristics of water in turquoise. In this paper, thermal property of the apatite pseudomorphic turquoise from Maanshan, Anhui Province, has been studied by using the thermogravimetric and thermal analysis （TG-DSC）, infrared fIR） spectrum and X--ray powder （XRD） diffraction. From room temperature to 1 100 ℃, its thermal phase transformation can be divided into six stages： 100- 200 ℃, the removal of the absorption water; 250--330 ℃, the release of the hydroxyl and lattice water; 330--750 ℃, the formation of non-crystalline structure, about 750 ℃, a new phase formed; 750--1 100 ℃, the generation of aluminum phosphate with tridymite structure, and 1 100 ℃, the degree of crystalline order of aluminum phosphate is improved. The color of pseudomorphic turquoise is controlled bythe structure, the existence form and total amount of water, together with the binding mode of water molecules.

关 键 词：假象绿松石 磷酸铝 热性能 

分 类 号：P619.28[天文地球—矿床学]