α-重氮羰基化合物在合成五元杂环化合物中的新应用  

The novel application of α-diazocarbonyl compounds in syntheses of five-membered heterocycles

作　　者：郑海林[1] 凌云嵩[1] 李斌[1] 赵树凯 

机构地区：[1]广西大学化学系

出　　处：《广州化学》1997年第2期51-59,共9页Guangzhou Chemistry

摘　　要：本文综述了α-氮羰基化合物在合成五元杂环化合物方面新的研究成果，分为四大类：类卡宾对X－H键的插入反应；类卡宾时π键的反应；经由isomnchnone的反应；经由叶利德的反应．This paper focuses on the novel application of α-diazocarbonyl compounds in syntheses of five-membered heterocyclic compounds. These reactions have been classified into four kinds: intramolecular carbenoid X-H insertions; Carbenoid additions to π-bonds；isomnchnone cycloadditions, and ylide formation and subsequent reactions.

关 键 词：α重氮羰基 五元杂环化合物 五节杂环 

分 类 号：O626.1[理学—有机化学] O626.2[理学—化学]