非离子水溶性膦铑配合物催化剂的XPS表征  

Characterization of Nonionic Water-soluble Phosphine Rhodium Complexes Catalyst by XPS

作　　者：王艳华[1] 金子林[1] 

机构地区：[1]天津大学化工系一碳化工国家重点实验室

出　　处：《Chinese Journal of Chemical Physics》1997年第3期276-279,共4页化学物理学报（英文）

基　　金：天津大学化工系一碳化工国家重点实验室开放基金

摘　　要：用Ｘ射线光电子能谱（ＸＰＳ）的分析方法，对非离子水溶性膦铑配合物ＲｈＣｌ３／ＴＰＰＰ的组成、结构进行表征。并且用曲线拟合分峰技术对配体ＴＰＰＰ、配合物ＲｈＣｌ３／ＴＰＰＰ催化剂中各元素的峰进行数据处理。结果表明配体ＴＰＰＰ与配合物ＲｈＣｌ３／ＴＰＰＰ比较，配合物中存在Ｒｈ－ＣＯ配位和Ｒｈ－Ｐ配位，通过ＸＰＳ分析测试结果推断，原位合成的ＲｈＣｌ３／ＴＰＰＰ配合物催化剂其结构表示为ＣｌＲｈ（ＣＯ）ｎ（ＴＰＰＰ）ｍ。The composition of nonionic water-soluble phosphine rhodium complexes RhCl 3/TPPP has been characterized,by using X-ray photoelectron spectroscopy.Every elemental peak in the ligand TPPP and the complexes RhCl 3/TPPP catalyst have been measured mathematically by means of the curve fitting technique.It was found that the ligand Rh-CO and Rh-P present in the complexes as compared with the ligand TPPP.The synthesized RhCl 3/TPPP complex formula ClRh(CO) n(TPPP) m was also deduced.

关 键 词：XPS 膦铑配合物 催化剂 铑膦配合物 

分 类 号：O643.36[理学—物理化学]