铂催化硅氢加成反应研究进展  

Research Progress on Platinum Catalyzed Hydrosilylation Reactions

作　　者：陈久军[1] 邵月刚[1] 

机构地区：[1]浙江新安化工集团股份有限公司有机硅研究所,浙江建德311600

出　　处：《有机硅材料》2008年第3期171-175,共5页Silicone Material

摘　　要：总结了近几十年来具有工业应用价值的有机硅化学中硅碳键的形成方法——Rochow直接法和硅氢加成法。围绕硅氢加成法,系统阐述了硅氢加成的机理并且介绍了三种表观均相催化剂(Speier催化剂、Karstedt催化剂、铂分子配合物)及异相催化剂。In the past several decades, several silicon-carbon forming methods in the organosilicon chemistry were developed into industrially valuable processes, including Rochow＇s direct synthesis and the hydrosilylation reaction. A complete review of the mechanism of hydrosilylation was provided, and three apparent homogeneous catalysts （such as Speier＇s catalyst, Karstedt＇s catalyst and platinum molecular complex） and heterogeneous catalysts were introduced.

关 键 词：硅氢加成反应 铂 含氢硅烷 烯烃 氯铂酸 乙烯基聚硅氧烷 

分 类 号：O643.32[理学—物理化学]