漆酚镍螯合高聚物热分解反应动力学研究  

作　　者：陈日耀[1] 胡炳环[1] 林金火[1] 

机构地区：[1]福建师范大学,福州350007

出　　处：《中国生漆》1997年第1期16-19,共4页Journal of Chinese Lacquer

基　　金：国家自然科学基金

摘　　要：用非等温热重法研究了漆酚镍螯合高聚物的热分解反应动力学，结果表明漆酚镍螯合高聚物热分解过程是一级反应，用Coats和Redfern法求得的热分解反应平均活化能和频率因子分别为70·95KJmol-1和377．2S-1。The thermal decomposition kinetics of urushiol-Ni chelate polymers has been studied by non-isothermal thermogravimetry. The results suggest that the thermal -decomposition kinetics of urushiol-Ni chelate polymers is first order. The average activation energy and the average pre-exponential factor of the thermal decompostion by Coats and Redfern method are 70.95 KJmoL-1 and 377. 2 S-1 respectively.

关 键 词：漆酚 镍螯合高聚物 热分解反应 动力学 

分 类 号：O631.22[理学—高分子化学] O630.1[理学—化学]