二烯丙基双酚S醚的合成与表征  

The Synthesis and Characterization of Diallyl Bisphenol Sulfone Ether

作　　者：夏志宇[1,2,3] 陈子纯[1,2,3] 冼定国 

机构地区：[1]北京化工大学 [2]香港理工大学应用生物化学系 [3]香港理工大学应用物理系

出　　处：《北京化工大学学报（自然科学版）》1997年第3期22-25,共4页Journal of Beijing University of Chemical Technology(Natural Science Edition)

摘　　要：以相转移催化法合成了单体二烯丙基双酚Ｓ醚（ＤＡＢＳＥ），采用ＦＴＩＲ，１Ｈ－ＮＭＲ对单体结构进行了验证。ＤＳＣ结果表明：ＤＡＢＳＥ的熔点为１３３℃，热聚合温度高达２８０℃，并具有较宽的聚合峰。Diallyl Bisphenol Sulfone Ether (DABSE) was synthesized by using the Phase Transfer Catalyst (PTC) method. The product was identified by FTIR and 1 H NMR spectra. The DSC results show that the compound melts at about 133℃ and that its thermal polymerization peak is wide with a maximum peak temperature at about 280℃.

关 键 词：二烯丙基 双酚S醚 DABSE 相转移催化 聚合 

分 类 号：O625.322[理学—有机化学] TQ243.24[理学—化学]