单手性臂石胆酸分子裂缝的微波合成  

Microwave Assisted Synthesis of Single Chiral Arm Molecular Clefts Based on Lithocholic Acid

作　　者：赵志刚[1] 

机构地区：[1]西南民族大学化学与环境保护工程学院,四川成都610041

出　　处：《合成化学》2008年第3期304-307,共4页Chinese Journal of Synthetic Chemistry

摘　　要：在微波辐射下,以石胆酸为隔离基,通过三光气桥连各种L-氨基酸甲酯,以较好的产率合成了一系列新的手性分子裂缝,其结构经1H NMR,IR,MS和元素分析确证。A series of new chiral molecular clefts in good yields were synthesized using lithocholic acid as a spacer by triphosgene to bridge different L-amino acid methyl esters under microwave irradiation. The structures were characterized by ^1H NMR, IR, MS and elemental analysis.

关 键 词：石胆酸 分子裂缝 分子识别 微波合成 

分 类 号：O641.3[理学—物理化学]