高分子微球在电化学领域的应用  

Applications of Polymer Microsphere in Electrochemistry

作　　者：韩利民[1] 索全伶[1] 洪海龙[1] 

机构地区：[1]内蒙古工业大学化工学院,呼和浩特010051

出　　处：《化学进展》2008年第6期931-935,共5页Progress in Chemistry

基　　金：国家自然科学基金项目(No20666003)资助

摘　　要：本文综述了近几年来高分子微球在电化学领域应用的研究进展。分别介绍了电场作用下微球悬浮液反射光谱的变化,包覆导电聚合物高分子微球的振荡电流和循环伏安特征以及二茂铁基高分子微球电极反应的粒径效应,并对各类微球悬浮液的电化学行为和电极反应模型进行阐述。综述表明高分子微球电化学具有广阔的应用前景。In this paper, the applications of redox-active polymer microspheres in electrochemistry are reviewed. Spectrum changing of surface-ionized microspheres with the change of extra-electric field, cyclic voltammetry and oscillated current of conductive polymer coated microspheres and size effect of ferrocenyl microspheres on electrode reaction are introduced respectively. The electrochemical behavior and electrode reaction model of polymer microspheres in suspension are elucidated, too. The electrochemistry of polymer microspheres will be applied extensively in molecular model field.

关 键 词：高分子微球 电化学 氧化还原 电荷传递 电极反应 

分 类 号：O631.2[理学—高分子化学] O646[理学—化学]