杯[4]芳烃及其Fries重排衍生物液膜传输金属离子的对比研究  

Comparative Study on the Abilities to Transport Metal Ions between 25,26,27,28-tetrahydroxycalix [4] Arene and Its Derivative

作　　者：史春越[1] 范平[2] 舒燕[1] 

机构地区：[1]沈阳化工学院应用化学学院,辽宁沈阳110142 [2]辽宁大学化学学院,辽宁沈阳110036

出　　处：《沈阳化工学院学报》2008年第2期97-99,共3页Journal of Shenyang Institute of Chemical Technolgy

摘　　要：以25,26,27,28-四羟基杯[4]芳烃为原料,经由Fries重排‘一锅法’合成5,11,17,23-四己酰基-25,26,27,28-四羟基杯[4]芳烃(杯[4]芳烃四己酮).研究了25,26,27,28-四羟基杯[4]芳烃和杯[4]芳烃四己酮作为载体对金属离子的液膜传输作用,进行了比较,并对传输机理作了探讨.5,11,17,23-tetrahexanoyl-25,26,27,28-tetrahydroxycalix [4] arene（p-hexanoylcalix [4] arene） was synthesized from 25,26,27,28-tetrahydroxycalix [4] arene and hexanoyl chloride by using one-pot procedure via Fries rearrangement. Comparative study on liquid membrane transport of metal ions by 25,26,27,28-tetrahydroxycalix [ 4 ] arene and p-hexanoylcalix [ 4 ] arene. The transport mechanism was preliminarily discussed.

关 键 词：杯芳烃 液膜传输 FRIES重排 

分 类 号：O622[理学—有机化学]