对甲氧基苯胺与丙烯腈的催化加成  

Catalyzed addition of p-methoxy-aniline and acrylonitrile

作　　者：谭晓燕[1] 叶翠层[1] 赵莹[1] 杨志[1] 

机构地区：[1]中南林业科技大学应用化学研究所,湖南株洲412006

出　　处：《化学研究与应用》2008年第5期557-560,共4页Chemical Research and Application

基　　金：中南林业科技大学引进人才科研基金(030114)资助项目;湖南省科技厅项目(2007FJ4156)

摘　　要：P-methoxy-N,N-bis(2-cyanoethyl)aniline was synthesized by using p-methoxyaniline,acrylonitrile,AlCl3 and BE.The experimental result had proved that AlCl3 and BE was an excellent catalyst system.The appropriate reactive condition is that AlCl3 was 20%(mol) of p-methoxyaniline,BE was 10%(mol) of p-methoxyaniline,the reaction temperature was 78℃ and the reaction time was 8 hours.The catalyst system had high catalyst efficiency and selectivity together with yield over 94%.P - methoxy - N, N - bis （2 - cyanoethyl） aniline was synthesized by using p - methoxyaniline, acrylonitrile, AlCl3 and BE. The experimental result had proved that AlCl3 and BE was an excellent catalyst system. The appropriate reactive condition is that AlCl3 was 20% （mol） of p - methoxyaniline, BE was 10% （mol） of p - methoxyaniline, the reaction temperature was 78℃ and the reaction time was 8 hours. The catalyst system had high catalyst efficiency and selectivity together with yield over 94%.

关 键 词：ALCL3 丙烯腈 对甲氧基-N N-二氰乙基苯胺 加成反应 

分 类 号：O623.7[理学—有机化学]