利用二维相关红外光谱研究竹原纤维的热微扰作用  

Study of Thermal Perturbation of Natural Bamboo Fiber by Two Dimensional Correlation Analysis and Fourier Transform Infrared Spectroscopy

作　　者：黄安民[1] 王戈[2] 周群[3] 刘君良[1] 孙素琴[3] 

机构地区：[1]中国林业科学研究院木材工业研究所,北京100091 [2]国际竹藤网络中心,北京100102 [3]清华大学化学系,北京100084

出　　处：《光谱学与光谱分析》2008年第6期1237-1241,共5页Spectroscopy and Spectral Analysis

基　　金：“十一五”科技支撑计划项目(2006BAD19B07,2006BAD19B04);中央级公益性科研院所基金(CAFINT2007C04);国家林业局“948”项目(2003-4-27)资助

摘　　要：采用红外光谱法和二维相关光谱分析技术,对竹原纤维的热微扰作用进行了研究。通过竹材和服用竹原纤维的红外光谱图的比较,可以看出,和竹材相比,服用竹原纤维木质素和半纤维素含量明显降低。从不同温度（50-120℃）服用竹原纤维的动态红外光谱图得出,在这个缓慢升温的过程中,温度只是一种微扰,并没有发生剧烈的氧化作用。最后,借助于二维相关光谱分析,研究了服用竹原纤维和竹材在温度微扰作用下,红外光谱中各基团的相关变化情况。二者的二维相关红外光谱分析结果表明,服用竹原纤维和竹材都在1 655 cm^-1处出现最强自相关峰,说明其对应的化学基团对于温度变化十分敏感。二者的区别在于,在800-1 300 cm^-1波段,竹原纤维只有几个较弱的自相关峰和交叉峰,而竹材在这一波段出现一个较强的5×5峰组,说明服用竹原纤维和竹材的化学成分具有显著的差别,其对热微扰的敏感性大大降低。初步的研究结果表明,二维相关红外分析可以作为分析服用竹原纤维热微扰过程中结构动态变化的一种新方法,也为竹原纤维氧化机理的研究提供了一种新手段。The Fourier transform infrared spectroscopy （FTIR） combined with generalized two-dimensional correlation analysis was applied to study the mini-heating process of natural bamboo fiber. The absorption peaks of natural bamboo fiber and bamboo in the FTIR spectra were different, which showed the contents of lignin and hemicelluloses of natural bamboo fiber was lower than those of bamboo. The changes in absorption peaks of natural bamboo fiber in the FTIR spectra at different temperatures were inconspicuous during heating up from 50 to 120 ℃, which showed that there was not oxidation reaction in natural bamboo fiber during the process. With the help of 2D correlation analysis, the changes of different groups of natural bamboo fiber and bamboo during heating process were reflected. The strongest autopeak of them was all aroused at 1 665 cm^-1 in synchronous spectrum. The difference was that there were several weak auto-peaks and cross peaks in the natural bamboo fiber, but in the bamboo, one stronger 5 × 5 group was aroused in the 833-1 230 cm^-1. Region the reason was the difference in chemistry composition and the change degree during heating process. In conclusion, the 2D correlation analysis of FTIR can be a new method to analyze the microcosmic dynamic change in the structure of natural bamboo fiber and bamboo during the mini-heating process and also offers an important theory gist for the study of oxidation mechanism of them.

关 键 词：二维相关分析 傅里叶红外光谱 竹原纤维 

分 类 号：O657.3[理学—分析化学]