金属-有机配位聚合物在催化性能上的研究进展  

Progress in Catalytic Metal-organic Coordination Polymers

作　　者：幸良淑[1] 杨明莉[2] 张新涛[1] 胡传彬[1] 

机构地区：[1]重庆大学化学化工学院 [2]重庆大学西南资源开发及环境灾害控制教育部重点实验室,重庆400044

出　　处：《材料科学与工程学报》2008年第3期489-492,共4页Journal of Materials Science and Engineering

基　　金：2005年重庆市院士基金资助项目(CSTC-2005AB6007);2007年教育部重点资助项目(107090)

摘　　要：多孔金属-有机配位聚合物(Metal-Organic Coordination Polymers-MOCPs)是一种新型功能材料,可通过其构件分子(金属离子和有机配体分子)的组合对孔穴大小、形状和表面特性进行调控,从而赋于它独特的结构和特性,在催化性能、分子识别、气体吸附、光学、磁性材料等方面具有诱人的发展前景。本文系统介绍了MOCPs在催化性能上的研究进展及其合成途径,并对MOCPs酶模拟体系在传感器方面的应用进行了展望。Porous metal organic coordination polymers （MOCPs） are a novel type of functional materials with particular structures and properties dependent on their cavity sizes, shapes, and surface characteristics, which are controllable by selecting and assembling their building block molecules, i.e. various metal ions and organic ligands. They are attractive for their fascinating potential applications in catalysis, molecular recognition, gas adsorption, optics or magnetic materials, etc. In this article. the current progress is systematically reviewed in catalytic MOCPs and the approaches to their synthesis. It is expected that the catalytic MOCPs, the mimic enzyme are used as a new sensing elements in sensors.

关 键 词：金属-有机配位聚合物 合成 催化 酶模拟 

分 类 号：O614.121[理学—无机化学] O643.36[理学—化学]