紫外光降解水中痕量NDMA的效能研究  

Efficiency of Photodecomposition of Trace NDMA in Water by UV Irradiation

作　　者：徐冰冰[1] 陈忠林[1] 齐飞[1] 马军[1] 

机构地区：[1]哈尔滨工业大学市政环境工程学院,哈尔滨150090

出　　处：《环境科学》2008年第7期1908-1913,共6页Environmental Science

基　　金：国家自然科学基金项目(50578052);教育部新世纪优秀人才支持计划项目(NCET-04-0321)

摘　　要：采用紫外光降解水中痕量亚硝基二甲胺(NDMA),研究了NDMA初始浓度、溶液pH值、光照面积、紫外光辐射强度以及水质对紫外光降解NDMA的影响.结果表明,紫外光能够有效降解水中的NDMA,紫外光解反应5 min,NDMA去除率可以达到97.5%.初始浓度对NDMA的光降解去除率影响不大.随着pH值升高,紫外光解NDMA的反应速率呈现下降趋势,低pH值条件下光量子产率较高,溶液pH=2.2时NDMA具有最大光降解速率.NDMA的去除率随着有效光照面积的增大而增大,紫外光辐射强度的增加有利于NDMA的去除.水质对紫外光降解NDMA具有一定的影响,在自来水和江水为背景的2种对比体系中,光解NDMA去除率分别为96.7%和94.8%.Efficiency of photodecomposition of trace NDMA by UV irradiation was investigated with analyzing the initial concentration of NDMA, solution pH, irradiation area, irradiation intensity and water quality effect on NDMA photolysis. NDMA could be effectively photodegraded by UV irradiation. The removal efficiency of NDMA was 97.5 % after 5 min of UV irradiation. Effect of initial NDMA concentration on photodecomposition of NDMA was not remarkable. With pH value ascending, the removal rate of NDMA photodecomposition decreased. The yields of photoquantum were more under lower solution pH than that under higher pH. NDMA had fastest reaction rate at solution pH = 2.2. Removal efficiency of NDMA increased with the available irradiation area ascending. Increscent ultraviolet irradiation intensity was good for NDMA degradation. Water quality affected the removal of NDMA slightly. The removal efficiency of NDMA in tap water and Songhua River raw water were 96.7% and 94.8%, respectively.

关 键 词：亚硝基二甲胺(NDMA) 紫外光 光降解 光量子产率 

分 类 号：X703.1[环境科学与工程—环境工程]