四氯化锆四元催化体系中乙烯齐聚反应的动力学研究  

The study of dynamics of ethylene oligomerization catalyzed by zirconium tetrachloride four-component catalyst

作　　者：徐乃进[1] 

机构地区：[1]大连医科大学化学教研室

出　　处：《广州化学》1997年第4期9-14,共6页Guangzhou Chemistry

摘　　要：研究了四氧化锆作主催化剂的四元催化体系中，乙烯压力、催化剂浓度和温度对乙烯齐聚反应的影响．测定了稳定态下乙烯齐聚反应的宏观动力学方程和表观活化能．The effects of ethylene pressure, catalyst concentration and reaction temperature on ethylene oligomerization in the presence of zirconium tetrachloride four-component catalyst were initially investigated. The macroscopic dynamic equation and apparentactivation energy for ethylene oligomerization were also determined in a stable state。

关 键 词：四氯化锆 催化 乙烯 齐聚 动力学 

分 类 号：O623.121[理学—有机化学] O643.32[理学—化学]