三异丙氧钐催化下醇的选择性乙酰化反应  

Selective Acetylation of Alcohols Catalyzed by Tri - 2 - propoxide Samarium

作　　者：付晓林[1] 吴世晖[1] 

机构地区：[1]复旦大学化学系,上海200433

出　　处：《有机化学》1997年第5期442-445,共4页Chinese Journal of Organic Chemistry

摘　　要：本文报道了三异丙氧钐(5％)催化下,以乙酸乙酯为乙酰化试剂醇的选择性乙酰化反应。此法操作简便,产率良好。This paper reports a simple, mild and convenient method for selective acetylation of primary alcohols in the presence of secondary alcohols using ethyl acetate as acetylated agent. These reactions are catalyzed by tri - 2 - propoxide samarium (5% ) with good to excellent yields.

关 键 词：乙酰化 催化 钐试剂 醇 三异丙氧钐 

分 类 号：O643.36[理学—物理化学] O622.3[理学—化学]