合成马来酸二丁酯催化剂的研究进展  

Research Progress of Catalyst in Sythesis of Dibutyl Maleate

作　　者：俞善信[1] 刘美艳[1] 管仕斌[1] 

机构地区：[1]湖南师范大学化学化工学院,湖南长沙410081

出　　处：《化学推进剂与高分子材料》2008年第4期1-5,共5页Chemical Propellants & Polymeric Materials

摘　　要：评述了对甲苯磺酸、氨基磺酸、强酸性阳离子交换树脂、六水三氯化铁、树脂固载三氯化铝、五水四氯化锡、十二水合硫酸铁铵、一水硫酸氢钠、硫酸铁、固体超强酸、杂多酸、钛酸酯、铌酸和分子筛等催化剂催化合成马来酸二丁酯的方法。认为氨基磺酸、一水硫酸氢钠、固体超强酸、杂多酸、铌酸、分子筛和固载型催化剂等是合成马来酸二丁酯具有实用价值的催化剂。The synthesis methods of dibutyl maleate catalyzed by p-toluene sulfonic acid, amino sulfonic acid, strongly acidic cationic exchange resin, ferric chloride hexahydrate, resin support aluminum chloride, stannic chloride pentahydrate, ammonium ferric sulfate dodecahydrate, sodium bisulfate monohydrate, ferric sulfate, solid super acid, heteropoly acid, titanate, niobic acid and molecular sieve etc. are reviewed. It is suggested that amino sulfonic acid, sodium bisulfate monohydrate, solid super acid, heteropoly acid, niobic acid, molecular sieve and support catalyst etc. are the practical catalysts for synthesizing dibutyl maleate.

关 键 词：马来酸二丁酯 合成 催化剂 

分 类 号：TQ225.24[化学工程—有机化工] TQ414