气相色谱法测定地下水中六六六结果的不确定度评定  

Uncertainty Evaluation of Measurement Results for the Determination of HCH in Groundwater Samples by Gas Chromatography

作　　者：李松[1] 饶竹[1] 

机构地区：[1]国家地质实验测试中心,北京100037

出　　处：《岩矿测试》2008年第4期295-298,共4页Rock and Mineral Analysis

基　　金：国土资源部地质大调查项目资助(200120190107-05);地质调查工作项目--地下水有机污染物分析技术研究项目资助(121201063460);国家地质实验测试中心基本科研项目资助(2008CSJ02)

摘　　要：依照《测量不确定度评定与表示》,对气相色谱法测定地下水中六六六(HCH)四种单体结果进行了不确定度评定。分析了测量过程中引入的不确定度来源,包括提取液体积的量取、样品提取溶液的定容体积、分析仪器的进样量、标准系列溶液的测量以及仪器重复测定等分量引入不确定度及其各参数的采集和计算方法,最后合成标准不确定度,通过乘以95%概率下的扩展因子2,获得测量结果的扩展不确定度。Based on 〈 Evaluation and Expression of Uncertainty in Measurement 〉, the measurement results of HCH in groundwater samples by gas chromatography （GC） were collected and the measurement uncertainty was evaluated. The sources of uncertainty produced in analysis process were discussed and the sampling volume for HCH extraction, volume fixing for HCH-extracted sample solution, sample volume introduced in GC instrument, measurement of the calibration standard solutions and the repetitive measurements of the instrument, etc. were considered as the main sources of the measurement uncertainty. The uncertainty expression parameters and mathematical models for calculating each parameter were also proposed. And the expanded uncertainty was obtained from synthesize standard uncertainty multiplied by expanded factor of 2 under the confidence level of 95%.

关 键 词：不确定度评定 六六六 气相色谱法 地下水 

分 类 号：O213.1[理学—概率论与数理统计] O657.71[理学—数学]