轴不稳定手性配体的开发及其在不对称催化反应中的应用  

Development of Axial-unfixed(Tropos) Ligands and Their Applications to Asymmetric Catalytic Reactions

作　　者：戴轶俊[1] 杨国强[1] 张勇健[1] 王飞军[1] 张万斌[1] 

机构地区：[1]上海交通大学化学化工学院,上海200240

出　　处：《有机化学》2008年第7期1169-1180,共12页Chinese Journal of Organic Chemistry

基　　金：高等学校博士学科点专项科研基金(No.20050248002)资助项目

摘　　要：轴不稳定配体应用于不对称催化有其独到的特点,不同于传统的轴稳定手性配体.综述了轴不稳定的噁唑啉、双膦、单膦、双羟基及N—O等配体的开发及其在不对称催化中的应用.Tropos ligands, compared with traditional atropos ligands, have unique characteristics. Here, the development of several major types of tropos ligands, including oxazoline, biphosphine, monophosphine, bihydroxyl and N--O ligands, and their applications to asymmetric catalysis are reviewed.

关 键 词：轴手性 轴不稳定配体 不对称催化 

分 类 号：O643.32[理学—物理化学]