新型含席夫碱大环化合物的合成  

Synthesis of Novel Schiff Base Macrocyclic Compound

作　　者：张奇龙[1] 朱兴城[1] 朱必学[1] 

机构地区：[1]贵州大学大环及超分子化学重点实验室,贵阳55002

出　　处：《有机化学》2008年第7期1254-1258,共5页Chinese Journal of Organic Chemistry

基　　金：贵州省国际合作重点项目(No.20062016);教育部春晖计划(No.2007152005)资助项目

摘　　要：以乙二胺、1,2-丙二胺、乙酰丙酮和2,5-二巯基-1,3,4-噻二唑为原料,经缩合、溴代和成环作用得到了两个新型席夫碱大环化合物6a和6b.用元素分析,1HNMR,IR和质谱进行表征,同时用X射线衍射方法测定了两个中间体的晶体结构.Two novel Schiff base macrocyclic compounds （6a and 6b） have been synthesized from ethylenediamine, 1,2-propane diamine, acetylacetone and 2,5-dimercapto-1,3,4-thiadiazole by condensation, bromination and cyclization, and their structures were characterized by elemental analysis, ^1H NMR, IR and MS techniques. Simultaneously, the crystal structures of two intermediates were determined by X-ray diffraction analysis.

关 键 词：乙酰丙酮 2 5-二巯基-1 3 4-噻二唑 大环化合物 晶体结构 

分 类 号：O626[理学—有机化学] TQ522.65[理学—化学]