含氧、氮、硫杂原子的螺环大分子化合物的研究进展  

Progress in Studying Spiro Macromolecular Compounds Containing O,N and S

作　　者：魏荣宝[1] 梁娅[1] 

机构地区：[1]天津理工大学化学化工学院,天津300191

出　　处：《有机化学》2008年第7期1287-1299,共13页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金(No.2047206);天津市自然科学基金(No.040884311)资助项目

摘　　要：近20年来,螺环大分子化合物由于其特殊的结构而引起了科学家们的广泛关注,作为一类新型的高负载量载体应用于有机合成和催化是螺环大分子化合物重要的应用领域之一.介绍了含氧、氮、硫等杂原子的线形及树形大分子螺环化合物的合成方法和结构特征,展望了该类化合物的应用前景,并提出了一些新的设想.During recent 20 years, spiro macromolecular compounds have drawn great attention because of their unique highly branched structures. A promising application of the spiro macromolecular compounds is that they can be used as high-loading supports for organic synthesis and catalysis. In this review, linear and dendrimer spiro macromolecular compounds containing O, N and S are described, focusing on the structural feature and synthesis method. Their potential application together with some novel application ideas is supplied.

关 键 词：螺环大分子化合物 树形化合物 季戊四醇 冠醚 

分 类 号：O621.3[理学—有机化学]