对氯苯甲酰芳肼化合物的合成及其氧化脱氢研究  

Synthesis and Dehydrogenation of Parachlorobenzoyl Acylhydrazines

作　　者：李晓波[1] 姜小莹[1] 李艳霞[1] 

机构地区：[1]河南科技学院化学化工学院,河南省新乡市华兰大道453003

出　　处：《光谱实验室》2008年第4期618-620,共3页Chinese Journal of Spectroscopy Laboratory

摘　　要：以取代苯肼、自制的对氯苯甲酰氯为原料,用冰浴法合成了2种对氯苯甲酰芳肼化合物;并用N-溴代丁二酰亚胺(NBS)/吡啶氧化体系脱氢得2种对氯苯甲酰芳基偶氮化合物,产品的结构经元素分析、IR、1HNMR确证,产率在80%—89%之间;所合成的化合物尚未见文献报道。Parachlorobenzoyl acylhydrazines were synthesized in ice bath with substituted hydrazine and parachlorobenzoyl chloride as raw materials. Parachlorobenzoic acyl azo compounds were synthesized firstly with the oxidation system NBS/Pyridine. The products were characterized by elementary analysis,IR and 1^HNMR. The yields of products were about from 80 % to 89 %.

关 键 词：对氯苯甲酰氯 取代苯肼 对氯苯甲酰芳肼 合成 氧化脱氢 

分 类 号：O657.33[理学—分析化学] O657.2[理学—化学]