羟基磷酸铜的快速绿色合成  

A Rapid and Green Method for Synthesis of Copper Hydroxyphosphate

作　　者：沈启慧[1] 邹永存[1] 万利丰[1] 刘文婷[1] 王润伟[1] 裘式纶[1] 

机构地区：[1]吉林大学化学学院

出　　处：《高等学校化学学报》2008年第7期1331-1333,共3页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金(批准号:20741001;20273026)资助

摘　　要：Copper hydroxyphosphate was rapidly synthesized by using a novel hydrothermal method, in which phosphoric acid and copper acetate hydrate are two mainly raw materials in the procedure of preparation without the presence of ethylenediamine. Compared with the conventional method, this new method cost less with less reaction time and without damage to environment. The resultant copper hydroxyphosphate samples were characterized by X-ray diffraction(XRD), single crystal X-ray diffraction and Leica optical microscopy. The as-synthesized samples show significant activities to the hydroxylation of phenol. The exposure of special crystal planes(011) and (101) can be used to explain the high hydroxylation activities of as-synthesized copper hydroxyphosphate at 80 ℃.Copper hydroxyphosphate was rapidly synthesized by using a novel hydrothermal method, in which phosphoric acid and copper acetate hydrate are two mainly raw materials in the procedure of preparation with- out the presence of ethylenediamine. Compared with the conventional method, this new method cost less with less reaction time and without damage to environment. The resultant copper hydroxyphosphate samples were characterized by X-ray diffraction（XRD）, single crystal X-ray diffraction and Leica optical microscopy. The as-synthesized samples show significant activities to the hydroxylation of phenol. The exposure of special crystal planes（011） and （101） can be used to explain the high hydroxylation activities of as-synthesized copper hydroxyphosphate at 80℃.

关 键 词：羟基磷酸铜 苯酚羟化 水热合成 

分 类 号：O611.4[理学—无机化学]