携带叠氮和氨侧基的脂肪族聚酯的合成和表征  

Synthesis and Characterization of Azido-and Amino-bearing Aliphatic Polyesters

作　　者：石全[1] 陈学思[1] 胡秀丽[1] 孙静[1] 肖海华[1] 景遐斌[1] 

机构地区：[1]中国科学院长春应用化学研究所

出　　处：《高等学校化学学报》2008年第7期1492-1494,共3页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金(批准号:20674084,50373043);国家自然科学杰出青年基金(批准号:50425309)资助

摘　　要：Functionalized aliphatic polyesters, especially those with pendent hydroxyl, carboxyl and amino groups, have attracted much research interest in recent years due to their perfect biocompatibility, biodegra-dability and reactivity. Copolymerization of lactide with functionalized cyclic carbonate monomers proved to be an efficient way to functionalize aliphatic polyesters. However, random co-polyesters with pendent amino groups were seldom reported. This article reported a facile way to prepare aliphatic polyesters with random pendant azido and amino groups via Click reaction.Functionalized aliphatic polyesters, especially those with pendent hydroxyl, carboxyl and amino groups, have attracted much research interest in recent years due to their perfect biocompatibility, biodegradability and reactivity. Copolymerization of lactide with functionalized cyclic carbonate monomers proved to be an efficient way to functionalize aliphatic polyesters. However, random co-polyesters with pendent amino groups were seldom reported. This article reported a facile way to prepare aliphatic polyesters with random pendant azido and amino groups via Click reaction.

关 键 词：脂肪族聚酯 叠氮 氨基 CLICK反应 环状碳酸酯 

分 类 号：O631[理学—高分子化学]