5-(ρ-β-乙酸乙酯基氨基苯基)-10,15,20-三苯基卟啉络钴(Ⅱ)的合成与表征  

Synthesis and characterization of 5-(ρ-β-ethyl acetate aminophenyl)-10,15,20-triphenyl porphyrin complexing Co(Ⅱ)

作　　者：张坤[1] 

机构地区：[1]阜阳师范学院化学化工学院,安徽阜阳236041

出　　处：《天津化工》2008年第4期25-26,共2页Tianjin Chemical Industry

基　　金：安徽省自然科学基金资助项目(050450301);安徽省教育厅自然科学基金资助项目(2006KJ123B)

摘　　要：5-(对-氨基苯基)-10,15,20-三苯基卟啉在无水碳酸钾和无水碘化钾催化下与氯乙酸乙酯进行亲核取代反应得到5-(ρ-β-乙酸乙酯基氨基苯基)-10,15,20-三苯基卟啉产率8.5%;其与Co(CH3COO)2反应得到5-(ρ-β-乙酸乙酯基氨基苯基)-10,15,20-三苯基卟啉络钴(Ⅱ),产率88.0%,其结构经UV-vsible、FT-IR、1HNMR和元素分析进行表征。5-（ρ-β-ethyl acetate aminophenyl）-10,15,20-triphenyl porphyrin was got in 8.5% yield through reacted with ethyl chloroacetate in the presence of anbydrous K2CO3 and KI,and 5-（ρ-β-ethyl acetate aminophenyl）-10,15,20 triphenyl porphyrin complexing Co （ Ⅱ ） was obtained in 88.0% yield through it reactde with Co（CH3COO）2.The structure of product was proved by UV-vsible,FT-IR,^1HNMR and elementary analysis.

关 键 词：氯乙酸乙酯 卟啉 合成 

分 类 号：O627[理学—有机化学]