金刚烷醚的便捷合成  

Convenient Synthesis of Adamantyl Ethers

作　　者：胡晓春[1] 孔黎春[1] 

机构地区：[1]浙江师范大学化学与生命科学学院,浙江金华321004

出　　处：《合成化学》2008年第4期467-469,471,共4页Chinese Journal of Synthetic Chemistry

基　　金：浙江省科技计划资助项目(2006C31028)

摘　　要：溴代金刚烷和醇在Ag2S04作用下，方便地合成了一系列的金刚烷单醚（收率70．6％-96．0％）和金刚烷二醚（收率35．0％-64．0％），其结构经^1HNMR和”CNMR表征。A series of adamantyl ethers were synthesized by the reaction of bromoadamantanes with alcohols in the presence of Ag2SO4. The yield of adamantyl monoethers and adamantyl diethers were 70.6% - 96.0% and 35.0% - 64.0%, respectively. The structures Were confirmed by ^1H NMR and ^13 C NMR.

关 键 词：金刚烷 醚 合成 

分 类 号：O624.11[理学—有机化学]