碱处理促进剩余污泥高温水解的试验研究  

Promoting High-Temperature Hydrolysis Under Alkaline Condition

作　　者：何玉凤[1] 杨凤林[1] 胡绍伟[1] 孙翠[1] 刘忠强[1] 宫正[1] 

机构地区：[1]大连理工大学环境与生命学院,大连116024

出　　处：《环境科学》2008年第8期2260-2265,共6页Environmental Science

基　　金：国家自然科学基金项目(50578023)

摘　　要：研究了热碱水解法对剩余污泥特性参数(溶解性化学需氧量、挥发性脂肪酸、氨氮、pH值与污泥浓度等)的影响.碱的加入减弱了污泥细胞壁对高温的抵抗力,加剧了剩余污泥细胞内有机质的释放与水解,改变了污泥的性质.在反应温度为170℃、pH 13、反应时间为75 min的条件下,溶解性化学需氧量(SCOD)达到了最大融出量17 956 mg/L,此时SCOD与总化学需氧量(TCOD)之比为0.65.在pH 13,反应时间为60 min时悬浮固体(SS)、挥发性悬浮固体(VSS)均达到了最大溶解率,其值分别为67%和72%.经热碱水解处理后的剩余污泥SCOD随着原污泥浓度的增大而增大,呈现了良好的线性关系,相关系数R2达到了0.97以上,而且随着pH值的增大,融出率也不断增大,在pH 13时达到最高值672 mg/g.另外,通过正交试验可以得出170℃时各因素对SCOD影响的重要性,依次为污泥浓度、pH值、反应时间.The effect of alkaline thermal hydrolysis method on excess sludge and its characteristic parameters（such as soluble chemical oxygen demand,volatile fatty acids,ammonia-nitrogen,pH value,sludge concentration,etc.） were investigated.The results show that the addition of alkali can reduce the resistance of the sludge cells to high temperature and enhance the release and the hydrolysis of organic materials from the sludge cells with the increase of temperature,pH value and reaction time.The concentration of SCOD reached17950mg/L and SCOD/TCOD was 0.65 on the conditions of pH 13,170℃ and 75 min.The maximal dissolving rate of suspended solids（SS） was 67% and 72% for volatile suspended solids（VSS） at pH 13 with 60 min.The concentration of SCOD after alkaline thermal hydrolysis treatment increased with the increase of sludge concentration,in which the nice linear relation was reached and the correlation coefficient（R^2） was above 0.97.The increasing rate of the SCOD was improving with the increase of the pH value and the SCOD of unit sludge reached 672mg/g at pH 13.The effect of three factors on the SCOD was investigated through orthogonal experiment at the temperature of 170℃,the importance was sludge concentration,pH value and reaction time in turn.

关 键 词：剩余污泥 热碱水解 PH值 

分 类 号：X705[环境科学与工程—环境工程]