2,4-二氰基和 2,4-二硝基五环[4.3.0.0^(2,5).0^(3,8).0^(4,7)]壬烷的热行为  

Thermal Behaviour of 2,4 dicyano and 2,4 dinitro pentacyclo [4.3.0.0 2,5 .0 3,8 .0 4,7 ]nonanes

作　　者：吴善祥[1] 胡荣祖[1] 康冰[1] 

机构地区：[1]西安近代化学研究所

出　　处：《火炸药》1997年第4期35-36,,38,,共3页

摘　　要：在线性升温条件下，用ＳＣ－ＤＳＣ研究了２，４－二氯基五环［４．３．０．０２，５．０３，８．０４，７］壬烷（ＤＣＰＣＮ）和２，４－二硝基五环［４．３．０．０２，５．０３，８．０４，７］壬烷（ＤＮＰＣＮ）的热行为。在我们的实验条件下，未检测到ＤＣＰＣＮ的熔化吸热峰，因此未得到ＤＣＰＣＮ的熔化过程热力学参数。测定了升温速率为零时，ＤＣＰＣＮ和ＤＮＰＣＮ放热分解反应的外推始点温度、峰温以及自发火温度和分解热值，文中还报道了题称物质的热分解反应动力学参数。The thermal behaviour of 2,4 dicyanopentacyclo[4.3.0.0 2,5 .0 3,8 .0 4,7 ]nonane (DCPCN) and 2,4 dinitropentacyclo[4.3.0.0 2,5 .0 3,8 .0 4,7 ]nonane(DNPCN) are studied by means of SC DSC under conditions of linear temperature increase. The corresponding values of DCPCN are not obtained because there is no melting peak on its DSC curve. The extrapolated onset temperature and peak temperature of the exothermic decomposition reaction corresponding to heating rate tends to zero, and spontaneous ignition temperature and decomposition heat. The values of the kinetic parameters are also reported for the exothermic decomposition of DCPCN and DNPCN.

关 键 词：高能量密度材料 晶转 热分解 DCPCN DNPCN 

分 类 号：TQ560.7[化学工程—炸药化工]