Electronic structure and physical properties of ScN in pressure: density-functional theory calculations  

作　　者：管鹏飞 王崇愚 于涛 

机构地区：[1]Central Iron and Steel Research Institute [2]China Centre of Advanced Science and Technology (World Laboratory) [3]Department of Physics, Tsinghua University

出　　处：《Chinese Physics B》2008年第8期3040-3053,共14页中国物理B（英文版）

基　　金：Project supported by the State Key Development Program for Basic Research of China (Grant No 2006CB605102)

摘　　要：Local density functional is investigated by using the full-potential linearized augmented plane wave （FP-LAPW） method for ScN in the hexagonal structure and the rocksalt structure and for hexagonal structures linking a layered hexagonal phase with wurtzite structure along a homogeneous strain transition path. It is found that the wurtzite ScN is unstable and the layered hexagonal phase, labelled as ho, in which atoms are approximately fivefold coordinated, is metastable, and the rocksalt ScN is stable. The electronic structure, the physical properties of the intermediate structures and the energy band structure along the transition are presented. It is found that the band gaps change from 4.0 to 1.0 eV continuously when c/a value varies from 1.68 to 1.26. It is noticeable that the study of ScN provides an opportunity to apply this kind of material （in wurtzite[h]-derived phase）.Local density functional is investigated by using the full-potential linearized augmented plane wave （FP-LAPW） method for ScN in the hexagonal structure and the rocksalt structure and for hexagonal structures linking a layered hexagonal phase with wurtzite structure along a homogeneous strain transition path. It is found that the wurtzite ScN is unstable and the layered hexagonal phase, labelled as ho, in which atoms are approximately fivefold coordinated, is metastable, and the rocksalt ScN is stable. The electronic structure, the physical properties of the intermediate structures and the energy band structure along the transition are presented. It is found that the band gaps change from 4.0 to 1.0 eV continuously when c/a value varies from 1.68 to 1.26. It is noticeable that the study of ScN provides an opportunity to apply this kind of material （in wurtzite[h]-derived phase）.

关 键 词：full-potential linearized augmented plane wave （FLAPW） band gap phase transition 

分 类 号：O469[理学—凝聚态物理]