Preparation and chiral recognitio of a novel chiral stationary phase for HPLC,based on mono(6~A-N-1-(2-hydroxyl)-phenylethylimino-6~A-deoxy)-β-cyclodextrin and covalently bonded silica gel  

作　　者：Xiao Ping Chen Zhi Ming Zhou Hao Yuan Zi Hui Meng 

机构地区：[1]School of Chemical Engineering and the Environment, Beijing Institute of Technology, Beijing 100081, China

出　　处：《Chinese Chemical Letters》2008年第7期797-800,共4页中国化学快报（英文版）

基　　金：Financial support from the National Natural Science Foundation of China (No.20572009)

摘　　要：A novel chiral stationary phase （CSP） was prepared by immobilizing mono（6A-N-1-（2-hydroxyl）-phenylethylimino-6A- deoxy）-β-cyclodextrin onto the surface of silica gel via a longer spacer. This chiral stationary phase exhibited good enantioselectivity for a variety of chiral compounds under reversed-phase conditions.A novel chiral stationary phase （CSP） was prepared by immobilizing mono（6A-N-1-（2-hydroxyl）-phenylethylimino-6A- deoxy）-β-cyclodextrin onto the surface of silica gel via a longer spacer. This chiral stationary phase exhibited good enantioselectivity for a variety of chiral compounds under reversed-phase conditions.

关 键 词：CYCLODEXTRIN Enandoseparation Chiral stationary phase Ferrocene derivatives 

分 类 号：O627.81[理学—有机化学]