An efficient method for the synthesis of dialkyl chlorophosphates from trialkyl phosphites using bis(trichloromethyl)carbonate  

作　　者：Bo Wang Chuan Ming Yu Zhi Wei Chen Wei Ke Su 

机构地区：[1]College of Pharmaceutical Sciences, Zhejiang University of Technology, Zhejiang Key Laboratory of Pharmaceutical Engineering, Hangzhou 310014, China

出　　处：《Chinese Chemical Letters》2008年第8期904-906,共3页中国化学快报（英文版）

基　　金：the National Basic Research Program of China 973 Program(No.2003CB114400);the National Natural Science Foundation of China(No.20476098);for financial support.(No.20676123)

摘　　要：A mild and simple method for the synthesis of dialkyl chlorophosphates is described, bis（trichloromethyl） carbonate （BTC） is used as the effective reagent for the conversion of dialkyl phosphites to their corresponding dialkyl chlorophosphates under mild conditions.A mild and simple method for the synthesis of dialkyl chlorophosphates is described, bis（trichloromethyl） carbonate （BTC） is used as the effective reagent for the conversion of dialkyl phosphites to their corresponding dialkyl chlorophosphates under mild conditions.

关 键 词：Bis（trichloromethyl） carbonate Dialkyl chlorophosphate Tdalkyl phosphite SYNTHESIS 

分 类 号：O622[理学—有机化学]