具有二维网格结构的5-(4-硝基苯基)四唑-锌(Ⅱ)配合物(英文)  

A Novel 2D Zn-coordination Polymer Based on a 5-(4-nitrophenyl)-1H-tetrazole Ligand

作　　者：肖杰[1] 赵玉媛[1] 王文祥[1] 赵红[1] 

机构地区：[1]f东南大学化学化工学院有序物质科学研究中心,南京211189

出　　处：《无机化学学报》2008年第8期1347-1351,共5页Chinese Journal of Inorganic Chemistry

基　　金：东南大学启动基金资助项目

摘　　要：A zinc(Ⅱ) complex [(5-(4-nitrophenyl)tetrazolato)2Zn]n was obtained by the hydrothermal treatment of ZnBr2 and NaN3 with 4-nitrobenzonitril in water at 120 ℃ in Pyrex tube. The crystal belongs to orthorhombic system with space group Pbcn, and a=1.040 7(5) nm, b=1.382 1(7) nm, c=2.435 1(13) nm, V=3.503(3) nm3, Z=8. This complex is a good blue fluorescent material in solid state at room temperature. CCDC: 684226.A zinc（Ⅱ） complex [（5-（4-nitrophenyl）tetrazolato）2Zn]n was obtained by the hydrothermal treatment of ZnBr2 and NaN3 with 4-nitrobenzonitril in water at 120 ℃ in Pyrex tube. The crystal belongs to orthorhombic system with space group Pbcn, and a=1.0407（5） nm, b=1.382 1（7） nm, c=2.435 1（13） nm, V=3.503（3） nm3, Z=8. This complex is a good blue fluorescent material in solid state at room temperature. CCDC： 684226.

关 键 词：锌配合物:水热合成 晶体结构 荧光性质 

分 类 号：O614.241[理学—无机化学]