高温煤气中羰基硫的加氢脱除研究进展  

Research progress of hydrodesulfurization of carbonyl sulfide in hot coal gas

作　　者：张海鹰[1] 王旭珍[1] 郑军[1] 赵宗彬[2] 

机构地区：[1]大连理工大学化工学院化学系,辽宁大连116023 [2]大连理工大学化工学院炭素材料研究室暨精细化工国家重点实验室,辽宁大连116012

出　　处：《应用化工》2008年第8期943-947,共5页Applied Chemical Industry

基　　金：国家重点基础研究发展规划项目"973"计划项目(2005CB221203-06)

摘　　要：综述了加氢转化法脱除高温煤气中COS的研究现状,从加氢转化催化剂镍、钴、钼系,具有转化和吸收双功能的脱硫剂(钙系、锌系、铁系、锰系、复合金属氧化物)以及改性活性炭基催化剂等方面进行了分析,并对相应的脱硫反应条件控制和现存问题进行讨论,提出了改进措施。Hydrodesulfurization of earbonyl sulfide （COS） in hot coal gas has been reviewed, COS in hot coal gas was studied from three respects, such as Ni, Co and Mo catalysts, bifunetional catalysts with conversion and absorption （Ca,Zn ,F e, Mn and composite metal oxides desulfurizers） and activated carbonbased catalysts. The control of desulfurization reaction conditions and weaknesses of catalysts were also analyzed and improved measures were pointed out.

关 键 词：羰基硫(COS) 加氢脱硫 高温煤气 

分 类 号：X701.3[环境科学与工程—环境工程] TQ426.94[化学工程]